[2]主持：多层核壳金属磷化物/碳/硫的构筑及抑制多硫化物穿梭效应的研究 (No.2019JQ671)，陕西省自然科学基础研究计划青年项目，2019.1--2020.12。

[3]主持：S/MxCoP/石墨烯复合材料的调控构建及其性能/机制研究（No.2018M64356），中国博士后科学基金面上项目，2018.11--2020.10。

[4]主持：基于核壳材料的构建抑制室温钠硫电池穿梭效应的机制研究 (No.GK201903042)，中央高校基金项目，2019.1--2020.12。

[5]第二参与人：热解废吸附剂一步构建双过渡金属氧/磷化物与硼氮硫共掺杂碳复合材料实现高效电催化分解水的热化学法研究，面上项目，2021.1-2024.12。

[6]西安建筑科技大学高层次人才引进项目资助.

论文期刊：

发表学术论文30余篇，申请/授权国家发明专利若干项，近年来的代表作如下：

(1) Gao T, Wang. W., Liu D, Ding W, ZhouY, Zhao X*, Liu Z*, Chen Yu*, Borate anion-intercalated NiV-LDHnanoflakes/NiCoP nanowires heterostructures for enhanced oxygen evolutionselectivity in seawater splitting. Advanced Functional Materials. 2024,34 (24), 2315949.

(2) Zhao X,* Dang Y, Ma H,* BaiP, Li W, and Liu Z *，HybridAscharite/Reduced Graphene Oxide with Polysulfide Adsorption Host for AdvancedLithium−Sulfur Batteries. Inorganic Chemistry 2024, 63, 3107−3117

(3) Zhao X*, Gao T, Ren W, Zhao C*, LiuZhi-Hong, Li Linbo, Highly active CoP-Co2N confined in nanocarbonenabling efficient electrocatalytic immobilizing-conversion of polysulfidetargeting high-rate lithium-sulfur batteries. Journal of Energy Chemistry 2022,75, 250-259.

(4)  Zhao X*, Gao T,Yuan Y, Fang Z, Hollow slightly oxidized CoP confined into flyover-type carbonskeleton with multiple channels as an effective adsorption-catalysis matrix forrobust Li-S batteries. Electrochimica Acta 2022, 422, 140512.

(5)X.Yuan,S.Qiu,and X.Zhao*,Covalent Fixing of MoS2 Nanosheets with SnS Nanoparticles Anchored on g‑C3N4/Graphene Boosting Fast Charge/Ion Transport for Sodium Ion Hybrid Capacitors, ACS Applied Materials & Interfaces 2021,13, 34238−34247.
(6)X.Yuan,X.Zhao,*S.Qiu,and Y.Song, Synergistic Engineering of Defects and Heterostructures Enhance Lithium/Sodium Storage Properties of F-SnO2-x-SnS2-x Nanocrystals Supported on N,S Graphene, Chemistry-A European Journal, 2021, 27,1280712814.
(7)Y. Song,X.Zhao,*and Z.Liu*, Surface selenium doped hollow heterostructure CoFe sulfide nanoboxes for enhancing oxygen evolution reaction and supercapacitors, Electrochimica Acta, 2021,374,137962.
(8)X. Zhao, Y.Li,C.Zhao*, Z.Liu*, Hierarchical Mo/MoS2(1-x-y)Px nanosheets assembled on P, Nc odoped carbonnanotubes for hydrogen evolution in both acidic and alkaline electrolytes, Small, 2020, 2004973.
(9)X. Zhao*, Y.Song, Z.Liu*, Kinetics enhanced hierarchical Ni2P1-xSx/Ni@carbon/graphene yolk shell microspheres boosting advanced sodium/potassium storage, Journal of Materials Chemistry A,2020, 8, 23994(1区，IF:11.301).
(10)X.Zhao,D.Luo,Y.Wang,Z.Liu*,Reduced graphene oxide supported CoP nanocrystals confined in porous nitrogen doped carbon nanowire for highly enhanced lithium/sodium storage and hydrogen evolution reaction,Nano Research,2019,12(11), 28722880.
(11)X.Zhao,Y.Jia,Z. Liu,* GO-Graphene ink Derived hierarchical 3D graphene architecture supported ultrasmall Fe3O4 nanoparticles as high performance electrodes fo rLi/Na ion batteries and supercapacitors.Journal of Colloid and InterfaceScience，2019,536,463473.
(12)YWang,X.Zhao*,Z.Liu*, Few layer WS2 nanosheets with oxygen incorporated defect sulphur entrapped by a hierarchical N,S codoped graphene network towards advanced long term lithium storage performances. RSC Advances,2020,10,7134.
(13)X.Zhao,G.Wang,X.Liu,X.Zheng,H.Wang*,Ultrathin MoS2 with expanded interlayers supported on hierarchical polypyrrole derived amorphous Ndoped carbontubular structures fo rhigh performance Li/Na ion batteries, Nano Research, 2018,11(7), 36033618.
(14)X.Zhao,G.Wang,*G.Zhai,H.Wang*，Facile assembly of 3D porous reduced graphene oxide/ultrathin MnO2 nanosheets aerogels as efficient polysulfide adsorption for high performance lithium sulfur batteries, Chemistry-A European Journal, 2017, 23(29), 70377045.
(15)X.Zhao,G.Wang,Y.Zhou,H.Wang*, Flexible freestanding ternary CoSnO3/graphene/carbonnanotubes composite papersas anodes for enhanced performance of lithium ion batteries. Energy, 2017,118,172180.
(16)懿倬，王艳，赵小军*，刘志宏*,一步硫/磷热处理制备空心Co9S8/CoP/C纳米复合材料及其储钠性能研究.中国科学，2020,51,112.

国家发明专利:

1. 赵小军，一种锡基氧化物/氮掺杂石墨烯复合材料及其制备方法和应用, 2022-8-23, 中国, 202211014748.8

2.赵小军，刘志宏 ; 一种氮磷掺杂碳纳米管@Mo/MoS2/MoP复合材料及其制备方法,2022-6-7, 中国, 201910990166.5

3.赵小军，刘志宏，罗丹; 一种CoP/氮掺杂碳/石墨烯纳米复合材料及其制备方法, 2020-11-17, 中国,ZL 2018 1 0699809.6

主编专著1部，参编无机丛书1部

1. 2024年获西安建筑科技大学第五届优秀教案展评校级二等奖。

2. 2022年获准国家级“大创”项目1项，结题优秀。

3. 2014年获安康市自然科学优秀学术论文奖。